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BRENDA KEGG MetaCyc

camphor degradation (BRENDA)

:= BRENDA, := KEGG, := MetaCyc, := SABIO-RK
:= amino acid sequences := show the reaction diagram
EC Number
Reaction
Pathways
Reaction IDs
Stoichiometry Check
Missing Substrate
Missing Product
Commentary
Remark
2,5-diketocamphane 1,2-monooxygenase
(+)-bornane-2,5-dione + FMNH2 + O2 = (+)-5-oxo-1,2-campholide + FMN + H2O
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natural substrates
3,6-diketocamphane 1,2-monooxygenase
(+)-bornane-2,5-dione + FMNH2 + O2 = (+)-5-oxo-1,2-campholide + FMN + H2O
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natural substrates
camphor 5-monooxygenase
(+)-camphor + reduced putidaredoxin + O2 = (+)-exo-5-hydroxycamphor + oxidized putidaredoxin + H2O
generic compounds
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: Oxidized putidaredoxin is re-reduced by NADH. (ec. 1.18.1.5)
natural substrates, generic
5-exo-hydroxycamphor dehydrogenase
5-exo-hydroxycamphor + NAD+ = bornane-2,5-dione + NADH + H+
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natural substrates
SPONTANEOUS
(+)-5-oxo-1,2-campholide = [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate + H+
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: spontaneous
natural substrates
0.0.0.0
spontaneous reaction
(+)-5-oxo-1,2-campholide = [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate + H+
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: spontaneous
natural substrates
(2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA synthase
[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate + ATP + CoA = AMP + diphosphate + [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA
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natural substrates
(2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA 1,5-monooxygenase
[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA + O2 + NADPH + H+ = [(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA + NADP+ + H2O
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natural substrates
[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA = DELTA2,5-3,4,4-trimethylpimeloyl-CoA + H+
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natural substrates
0.0.0.0
spontaneous reaction
[(2R)-3,3,4-trimethyl-6-oxo-3,6-dihydro-1H-pyran-2-yl]acetyl-CoA = DELTA2,5-3,4,4-trimethylpimeloyl-CoA + H+
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natural substrates